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Assessment and prediction of the mechanical properties of ternary geopolymer concrete

Jinliang LIU; Wei ZHAO; Xincheng SU; Xuefeng XIE

《结构与土木工程前沿（英文）》 2022年第16卷第11期页码 1436-1452 doi: 10.1007/s11709-022-0889-y

摘要： This paper utilized granulated blast furnace slag (GBFS), fly ash (FA), and zeolite powder (ZP) as the binders of ternary geopolymer concrete (TGC) activated with sodium silicate solution. The effects of alkali content (AC) and alkaline activator modulus (AAM) on the compressive strength, flexural tensile strength and elastic modulus of TGC were tested and the SEM micrographs were investigated. The experimental results were then compared with the predictions based on models of mechanical properties, and the amended models of TGC were proposed taking account of the effects of AC and AAM. The results indicated that increasing AC and reducing AAM which were in the specific ranges (5% to 7% and 1.1 to 1.5, respectively) had positive effects on the mechanical properties of TGC. In addition, the flexural tensile strength of TGC was 27.7% higher than that of OPC at the same compressive strength, while the elastic modulus of TGC was 25.8% lower than that of OPC. Appropriate prediction models with the R² of 0.945 and 0.987 for predicting flexural tensile strength and elastic modulus using compressive strength, respectively, were proposed. Fitting models, considering the effects of AC and AAM, were also proposed to predict the mechanical properties of TGC.

关键词： Ternary Geopolymer Concrete (TGC) alkaline activator modulus alkali content mechanical properties assessment

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Layered alkali titanates (ATiO): possible uses for energy/environment issues

《能源前沿（英文）》 2021年第15卷第3期页码 631-655 doi: 10.1007/s11708-021-0776-6

摘要： Uses of layered alkali titanates (A₂Ti_nO₂_n₊₁; Na₂Ti₃O₇, K₂Ti₄O₉, and Cs₂Ti₅O₁₁) for energy and environmental issues are summarized. Layered alkali titanates of various structural types and compositions are regarded as a class of nanostructured materials based on titanium oxide frameworks. If compared with commonly known titanium dioxides (anatase and rutile), materials design based on layered alkali titanates is quite versatile due to the unique structure (nanosheet) and morphological characters (anisotropic particle shape). Recent development of various synthetic methods (solid-state reaction, flux method, and hydrothermal reaction) for controlling the particle shape and size of layered alkali titanates are discussed. The ion exchange ability of layered alkali titanate is used for the collection of metal ions from water as well as a way of their functionalization. These possible materials design made layered alkali titanates promising for energy (including catalysis, photocatalysts, and battery) and environmental (metal ion concentration from aqueous environments) applications.

关键词： layered alkali titanates photocatalysis hydrogen evdution metal ions collection

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碱硅酸反应与碱碳酸盐反应

唐明述

《中国工程科学》 2000年第2卷第1期页码 34-40

摘要：

碱集料反应（AAR）可分为两类，即碱硅酸反应（ASR）与碱碳酸盐反应（ACR）。二者的共同点是与碱发生的化学反应可导致混凝土中集料的体积增大，从而可能使混凝土甚至整个建筑物或构筑物发生膨胀开裂。文章着重从膨胀过程和机理以及岩石的结构特征探讨二者的特性与差异。ASR类型岩石具有碱活性的前提条件是较低的二氧化硅结晶完整度。只有隐晶质、微晶质、玻璃质或发生过应变的二氧化硅才会具有较高的化学活性，导致混凝土破坏。通过系统研究证实，对碱碳酸盐反应，虽然结晶的完整程度以及白云石（CaCO₃·MgCO₃）分子式中Ca/Mg比也将影响其与碱反应的速率，但起决定作用的是白云石晶体的尺寸及其在岩石中的分布状态和被基质包围的紧密程度。从微观结构得出的这些特征将有助于加深对碱集料反应膨胀机理的认识。文中还介绍了形成活性白云石的地质环境和碱硅酸反应与碱碳酸盐反应的区分方法。

关键词：碱集料硅酸碳酸盐混凝土开裂机理

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基于BH-1模拟月壤的低碱高强地聚合物的制备与表征 Article

周思齐, 鲁乘鸿, 朱兴一, 李峰

《工程（英文）》 2021年第7卷第11期页码 1631-1645 doi: 10.1016/j.eng.2020.10.016

摘要：

建设月球基地以支持月面科研任务和资源利用一直是各国研究人员的目标。使用月球材料进行原位资源利用制备建筑材料对于节省昂贵的太空运费具有重要意义。本文研制了一种新型模拟月壤，名为北航（BH）-1。通过X射线荧光光谱（XRF）、X射线衍射（XRD）、扫描电子显微镜（SEM）和反射光谱结果证实，BH-1 的化学矿物组成和微观结构与真实月壤非常相似。本研究还在模拟月球环境条件下合成了一种基于BH-1 模拟月壤的地聚合物，并研究了补充铝源对地聚合物强度的影响。测定了碱激发BH-1 浆体的流变性能。采用XRF、XRD、傅里叶红外光谱、SEM能谱分析和27Al 魔角旋转核磁共振分析对地聚合物进行表征。试验结果表明，BH-1 浆体的流变曲线符合Herschel-Bulkley 模型，表现为剪切变稀流体。添加铝源的BH-1 地聚合物与对照组相比，28 天抗压强度可提高100.8%。同时，产生单位强度所需的添加剂的质量降低，显著减少了从地球运输至月球用于地聚合物制备的材料质量，有望节约太空运输成本。微观实验分析表明，通过添加额外的铝源来改善BH-1 地聚合物的力学性能机理为：促进了硅氧基中铝原子基团对硅原子基团的取代作用，生成更致密的无定形凝胶结构。

关键词：深空探测月球基地地聚合物模拟月壤流变学

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The development of ultralightweight expanded perlite-based thermal insulation panel using alkali activator

Damla Nur ÇELİK; Gökhan DURMUŞ

《结构与土木工程前沿（英文）》 2022年第16卷第11期页码 1486-1499 doi: 10.1007/s11709-022-0881-6

摘要： The International Energy Agency (IEA) states that global energy consumption will increase by 53% by 2030. Turkey has 70% of the world’s perlite reserves, and in order to reduce energy consumption a thermal insulation panel was developed in Turkey using different particle sizes of expanded perlite (EP). In this study, 0–1.18 mm (powder) and 0–3 mm (granular) EP particle sizes were selected, since they have the lowest thermal conductivity coefficients among all the particle sizes. In addition, an alkali activator solution was used as a binder in the mixtures. The alkaline activator solution was obtained by mixing sodium hydroxide solution (6, 8, 10, and 12 mol·L⁻¹) and sodium silicate (Module 3) at the different ratios of Na₂SiO₃ to NaOH of 1, 1.5, 2, and 2.5. This study aimed to experimentally determine the optimum binder and distribution ratio of EP, with the lowest coefficient of thermal conductivity and the lowest density. The lowest thermal conductivity and the lowest density were determined as 0.04919 W·m⁻¹·K⁻¹ and 133.267 kg/m³, respectively, in the sample prepared with 83.33% powder-size EP, 6 mol·L⁻¹ sodium hydroxide solution, and ratio of Na₂SiO₃ to NaOH of 1.5. The density, thermal conductivity, and compressive strength of the sample showed the same trends of behavior when the Na₂SiO₃ to NaOH ratio was increased. In addition, the highest compressive strength was measured in 12 mol·L⁻¹ NaOH concentration regardless of particle size. In conclusion, the study predicts that the EP-based thermal insulation panel can be used as an insulation material in the construction industry according to the TS825 Thermal Insulation Standard.

关键词： expanded perlite alkali activator thermal insulation panel thermal conductivity

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Utilization of alkali-activated copper slag as binder in concrete

《结构与土木工程前沿（英文）》 2021年第15卷第3期页码 773-780 doi: 10.1007/s11709-021-0722-z

摘要： This study was focused on developing concrete using alkali-activated copper slag (AACS) as a binder. The properties of alkali-activated copper slag concrete (AACSC) were compared with portland cement concrete (PCC). Different AACSC mixes were prepared with varying Na₂O dosage (6% and 8% of the binder by weight) and curing methods. Hydration products in AACSC were retrieved using Fourier-transform infrared spectroscopy (FTIR) and X-ray powder diffraction (XRD) techniques. The test results indicate that the workability of AACSC was lesser than that of PCC. The AACSC mix with 6% Na₂O dosage has exhibited similar mechanical properties as that of PCC. The mechanical properties of AACSC were higher than PCC when 8% of Na₂O dosage was used. Heat curing was effective to upgrade the strength properties of AACSC at an early age of curing, but at a later age mechanical properties of ambient cured and heat-cured AACSC were comparable. The hydration products of AACSC were not identified in XRD patterns, whereas, in FTIR spectra of AACSC some alkali-activated reaction products were reflected. The AACSC mixes were found to be more sustainable than PCC. It has been concluded that AACSC can be produced similarly to that of PCC and ambient curing is sufficient.

关键词： binder concrete mechanical properties mineralogy workability

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Molecular regulation and genetic improvement of seed oil content in

Wei HUA,Jing LIU,Hanzhong WANG

《农业科学与工程前沿（英文）》 2016年第3卷第3期页码 186-194 doi: 10.15302/J-FASE-2016107

摘要： As an important oil crop and a potential bioenergy crop, L. is becoming a model plant for basic research on seed lipid biosynthesis as well as seed oil content, which has always been the key breeding objective. In this review, we present current progress in understanding of the regulation of oil content in , including genetics, biosynthesis pathway, transcriptional regulation, maternal effects and QTL analysis. Furthermore, the history of breeding for high oil content in is summarized and the progress in breeding ultra-high oil content lines is described. Finally, prospects for breeding high oil content cultivars are outlined.

关键词： breeding maternal effects oilseed rape QTL

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碱激发矿渣混凝土的水化特性及微观结构研究进展 Review

傅强,卜梦鑫, 张兆瑞, 许文瑞, 元强, 牛荻涛

《工程（英文）》 2023年第20卷第1期页码 162-179 doi: 10.1016/j.eng.2021.07.026

摘要：

碱激发矿渣混凝土（alkali-activated slag concrete, AASC）是一种新型的绿色建材，与普通硅酸盐混凝土相比，

关键词：碱激发矿渣混凝土水化特性孔结构界面过渡区微观结构

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The Decarbonization of Construction—How Can Alkali-Activated Materials Contribute?

John L. Provis,Susan A. Bernal,Zuhua Zhang,

《工程（英文）》 doi: 10.1016/j.eng.2023.09.014

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井下裂缝连通技术在安棚碱矿的应用

齐铁新,刘建中,秦桂林,董峰

《中国工程科学》 2006年第8卷第7期页码 63-67

摘要：

介绍了在桐柏安棚碱矿，用微地震监测结合水准测量监测与注水井连通的原生裂隙带的理论、技术、方法和监测结果，并据此部署开采井位，把采液井打在与注水井连通的裂隙带上，实现了2条注、采井1 000m米井下裂隙带连通,使安棚碱矿可以连续注水、采出碱液，从而获得较高的生产水平和经济效益。

关键词：安棚碱矿湿法采碱井底裂缝连通水准测量微地震监测

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Modeling of alkali-silica reaction in concrete: a review

J.W. PAN, Y.T. FENG, J.T. WANG, Q.C. SUN, C.H. ZHANG, D.R.J. OWEN

《结构与土木工程前沿（英文）》 2012年第6卷第1期页码 1-18 doi: 10.1007/s11709-012-0141-2

摘要： This paper presents a comprehensive review of modeling of alkali-silica reaction (ASR) in concrete. Such modeling is essential for investigating the chemical expansion mechanism and the subsequent influence on the mechanical aspects of the material. The concept of ASR and the mechanism of expansion are first outlined, and the state-of-the-art of modeling for ASR, the focus of the paper, is then presented in detail. The modeling includes theoretical approaches, meso- and macroscopic models for ASR analysis. The theoretical approaches dealt with the chemical reaction mechanism and were used for predicting pessimum size of aggregate. Mesoscopic models have attempted to explain the mechanism of mechanical deterioration of ASR-affected concrete at material scale. The macroscopic models, chemo-mechanical coupling models, have been generally developed by combining the chemical reaction kinetics with linear or nonlinear mechanical constitutive, and were applied to reproduce and predict the long-term behavior of structures suffering from ASR. Finally, a conclusion and discussion of the modeling are given.

关键词： alkali-silica reaction (ASR) modeling concrete mesoscopic macroscopic

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Operando modeling and measurements: Powerful tools for revealing the mechanism of alkali carbonate-based

《能源前沿（英文）》 2023年第17卷第3期页码 380-389 doi: 10.1007/s11708-023-0872-x

摘要： Alkali carbonate-based sorbents (ACSs), including Na₂CO₃- and K₂CO₃-based sorbents, are promising for CO₂ capture. However, the complex sorbent components and operation conditions lead to the versatile kinetics of CO₂ sorption on these sorbents. This paper proposed that operando modeling and measurements are powerful tools to understand the mechanism of sorbents in real operating conditions, facilitating the sorbent development, reactor design, and operation parameter optimization. It reviewed the theoretical simulation achievements during the development of ACSs. It elucidated the findings obtained by utilizing density functional theory (DFT) calculations, ab initio molecular dynamics (AIMD) simulations, and classical molecular dynamics (CMD) simulations as well. The hygroscopicity of sorbent and the humidity of gas flow are crucial to shifting the carbonation reaction from the gas−solid mode to the gas−liquid mode, boosting the kinetics. Moreover, it briefly introduced a machine learning (ML) approach as a promising method to aid sorbent design. Furthermore, it demonstrated a conceptual compact operando measurement system in order to understand the behavior of ACSs in the real operation process. The proposed measurement system includes a micro fluidized-bed (MFB) reactor for kinetic analysis, a multi-camera sub-system for 3D particle movement tracking, and a combined Raman and IR sub-system for solid/gas components and temperature monitoring. It is believed that this system is useful to evaluate the real-time sorbent performance, validating the theoretical prediction and promoting the industrial scale-up of ACSs for CO₂ capture.

关键词： CO₂ capture carbonation theoretical modeling operando techniques reaction visualization

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Comparison of analytical procedures for measuring phosphorus content of animal manures in China

null

《农业科学与工程前沿（英文）》 2019年第6卷第4期页码 431-440 doi: 10.15302/J-FASE-2019279

摘要：

The concentration and components of manure phosphorus (P) are key factors determining potential P bioavailability and runoff. The distribution of P forms in swine, poultry and cattle manures collected from intensive and extensive production systems in several areas of China was investigated with sequential fractionation and a simplified two-step (NaHCO -NaOH/EDTA) procedures. The mean total P concentration, determined by the sequential fractionation procedure of intensive swine, poultry and cattle manure, expressed as g·kg , was 14.9, 13.4 and 5.8 g·kg , respectively, and 4.4 g·kg in extensive cattle manure. In intensive swine, poultry and cattle manure about 73%, 74% and 79% of total P, respectively, was bioavailable (i.e., P extracted by H O and NaHCO ) and 78% in extensive cattle manure. The results indicated the relative environmental risk, from high to low, of swine, poultry and cattle manure. There is considerable regional variation in animal manure P across China, which needs to be considered when developing manure management strategies.

关键词： diet phosphorus manure phosphorus sequential P fractionation

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Chloride binding and time-dependent surface chloride content models for fly ash concrete

S. MUTHULINGAM,B. N. RAO

《结构与土木工程前沿（英文）》 2016年第10卷第1期页码 112-120 doi: 10.1007/s11709-015-0322-x

摘要： Corrosion of embedded rebars is a classical deterioration mechanism of reinforced concrete structures exposed to chloride environments. Such environments can be attributed to the presence of seawater, deicing or sea-salts, which have high concentrations of chloride ion. Chloride ingress into concrete, essential for inducing rebar corrosion, is a complex interaction between many physical and chemical processes. The current study proposes two chloride ingress parameter models for fly ash concrete, namely: 1) surface chloride content under tidal exposure condition; and 2) chloride binding. First, inconsistencies in surface chloride content and chloride binding models reported in literature, due to them not being in line with past research studies, are pointed out. Secondly, to avoid such inconsistencies, surface chloride content and chloride binding models for fly ash concrete are proposed based upon the experimental work done by other researchers. It is observed that, proposed models are simple, consistent and in line with past research studies reported in literature.

关键词： binding isotherms chloride ingress concrete fly ash surface chloride content

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Microbial fuel cell with high content solid wastes as substrates: a review

Qingliang Zhao,Hang Yu,Weixian Zhang,Felix Tetteh Kabutey,Junqiu Jiang,Yunshu Zhang,Kun Wang,Jing Ding

《环境科学与工程前沿（英文）》 2017年第11卷第2期 doi: 10.1007/s11783-017-0918-6

摘要： Fundamentals and configuration design of MFCs fueled by HCSW were reviewed. HCSWs including sewage sludge, biomass and biowaste treated in MFCs were summarized. HCSW based MFCs technologies covered the types of sediment, soil, wetland and plant. Activated sludge process and composting could be coupled with HCSW-MFCs. HCSW-MFCs could be applied in bioremediation and biosensing. With the increasing concern about the serious global energy crisis and high energy consumption during high content solid wastes (HCSWs) treatment, microbial fuel cell (MFC) has been recognized as a promising resource utilization approach for HCSW stabilization with simultaneous electrical energy recovery. In contrast to the conventional HCSW stabilization processes, MFC has its unique advantages such as direct bio-energy conversion in a single step and mild reaction conditions (viz., ambient temperature, normal pressure, and neutral pH). This review mainly introduces some important aspects of electricity generation from HCSW and its stabilization in MFC, focusing on: (1) MFCs with different fundamentals and configurations designed and constructed to produce electricity from HCSW; (2) performance of wastes degradation and electricity generation; (3) prospect and deficiency posed by MFCs with HCSW as substrates. To date, the major drawback of MFCs fueled by HCSW is the lower power output than those using simple substrates. HCSW hydrolysis and decomposition would be a major tool to improve the performance of MFCs. The optimization of parameters is needed to push the progress of MFCs with HCSW as fuel.

关键词： Microbial fuel cell High content solid wastes Substrate Bioremediation Biosensor